Ni-Catalyzed Intermolecular C(sp3)–H Amidation Tuned by Bidentate Directing Groups
收藏Figshare2021-02-23 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Ni-Catalyzed_Intermolecular_C_sp_sup_3_sup_H_Amidation_Tuned_by_Bidentate_Directing_Groups/14096810
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We disclose herein a directing group-assisted nickel-catalyzed intermolecular C(sp3)–H amidation using organic azides as nitrene precursors. With the installation of an electronically tailored directing group, enhanced amidation efficiency was achieved. A series of experimental and computational studies suggested that a putative nickel(III)-nitrenoid species is a key intermediate in the C–N bond-forming process.
创建时间：
2021-02-23
