Ni-Catalyzed Intermolecular C(sp3)–H Amidation Tuned by Bidentate Directing Groups
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We disclose herein a directing group-assisted nickel-catalyzed intermolecular C(sp3)–H amidation using organic azides as nitrene precursors. With the installation of an electronically tailored directing group, enhanced amidation efficiency was achieved. A series of experimental and computational studies suggested that a putative nickel(III)-nitrenoid species is a key intermediate in the C–N bond-forming process.
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2021-02-23
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