Total Syntheses of (−)-Hibiscone C and Lysergine: A Cyclization/Fragmentation Strategy
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https://figshare.com/articles/dataset/Total_Syntheses_of_-Hibiscone_C_and_Lysergine_A_Cyclization_Fragmentation_Strategy/4572820
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资源简介：
The
first asymmetric total synthesis of (−)-hibiscone C
and a concise synthesis of ergot alkaloid lysergine are described.
Both syntheses were achieved using the radical cyclization/fragmentation
strategy. This cascade reaction enabled the application of the strained
bicycle as a synthon for the synthesis of highly substituted decalins
in an efficient and stereoselective manner.
创建时间：
2017-01-20
