Two Copper(II) Metal–Organic Frameworks with Nanoporous Channels and Vacant Coordination Sites
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Two_Copper_II_Metal_Organic_Frameworks_with_Nanoporous_Channels_and_Vacant_Coordination_Sites/2286397
下载链接
链接失效反馈官方服务：
资源简介：
Two
three-dimensional microporous compounds, Cu6(BTTC)4(H2O)6·xS (1) and [(CH3)2NH2]3[(Cu4Cl)3(BTTC)8]·yS (2, H3BTTC
= benzo-(1,2;3,4;5,6)-tris (thiophene-2′-carboxylic acid),
S represents noncoordinated solvent molecules), have been solvothermally
synthesized and characterized, both of which are based upon truncated
octahedron subunits and contain uniform nanosized cavities but exhibit
different topological frameworks. Complex 1 demonstrates
high adsorption enthalpies for H2 and CO2 gas
molecules, stemming principally from the presence of the exposed metal
Cu(II) sites on the pore surface. In particular, activated complex 1 shows high efficiency for the separation of energy-correlated
molecules, including CO2 over N2 and CH4 under ambient conditions.
创建时间：
2016-02-17
