Hybrid van der Waals MxRuCl3 materials (M – Mn, Fe, Co, Ni) from soft electrochemical synthesis: impact of transition metals on structure an

Name: Hybrid van der Waals MxRuCl3 materials (M – Mn, Fe, Co, Ni) from soft electrochemical synthesis: impact of transition metals on structure an
Creator: Karlsruhe Institute of Technology, Institut fuer Anorganische Chemie, Engesserstrasse 15, 76131, Karlsruhe, GERMANY; IFW Dresden, Helmholtzstrasse 20, 01069 , Dresden, GERMANY
Published: 2028-01-01 00:00:00
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https://doi.esrf.fr/10.15151/ESRF-ES-2261334117

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One possible strategy to tune magnetic properties of layered honeycomb-type materials with magnetic metal cations is an ion intercalation between neighboring layers. Using this approach, two parameters will be changed: a charge of the metal cations, and the interlayer distance. In the proposal, we plan investigations of MxRuCl3 (0≤x≤1) electronic structure after electrochemical intercalation of magnetic double-charged 3d transition metal cations into antiferromagnetic RuCl3, using XANES and EXAFS measurements at the K-edge of 3d metals, and at the Ru L2/L3-edge. Co-intercalation of H2O molecules will be investigated as well. Impact of inserted cations will be evaluated and brought together with detailed magnetic studied performed at the home institute.

提供机构：

Karlsruhe Institute of Technology, Institut fuer Anorganische Chemie, Engesserstrasse 15, 76131, Karlsruhe, GERMANY; IFW Dresden, Helmholtzstrasse 20, 01069 , Dresden, GERMANY

创建时间：

2028-01-01