Polysubstituted 2‑Aminopyrrole Synthesis via Gold-Catalyzed Intermolecular Nitrene Transfer from Vinyl Azide to Ynamide: Reaction Scope and Mechanistic Insights
收藏Figshare2016-02-12 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Polysubstituted_2_Aminopyrrole_Synthesis_via_Gold_Catalyzed_Intermolecular_Nitrene_Transfer_from_Vinyl_Azide_to_Ynamide_Reaction_Scope_and_Mechanistic_Insights/2106691
下载链接
链接失效反馈官方服务：
资源简介：
A gold-catalyzed intermolecular reaction of vinyl azides and ynamides is described. This process presents an efficient and mild approach to multisubstituted 2-aminopyrroles in good-to-excellent yields. Control experiments were carried out to distinguish the reactivity between vinyl azides and the corresponding 2H-azirines. A plausible reaction mechanism was also proposed according to previous reports and our preliminary mechanistic studies.
创建时间：
2016-02-12
