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Replication data for: Understanding Synthetic Peculiarities of Cationic Molyb...

B2FIND2026-03-19 收录

钼亚胺基烷基idene配合物合成

NHC配体化学

数据链接：

https://b2find.eudat.eu/dataset/a22be270-05a2-599e-b49b-ba4fb56dda23 数据链接链接失效反馈

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资源简介：

Data on novel synthetic approaches to molybdenum imido alkylidene N‐heterocyclic carbene (NHC) complexes including the first NHC alkylidene complexes featuring...

应用场景：

金属亚烷基化学

NHC配体化学

A ruthenium complex coordinated by a bidentate aryloxy-NHC ligand has offered the first example of an imidazolium-substituted metal alkylidene, an analogue of existing phosphonium alkylidenes and meta

NIAID Data Ecosystem50

Preparation of Rhodium(III) Di-NHC Chelate Complexes Featuring Two Different NHC Donors via a Mild NaOAc-Assisted C–H Activation

有机金属合成

NHC配体化学

Two molecules of 4,5-dichloroimidazole react with dibromomethane to give the diimidazole 1. Reaction of 1 with iodomethane or 2-fluorobenzyl bromide yields the monoalkylated imidazolium/imidazole salt

NIAID Data Ecosystem20

Carbene-Stabilized Phosphorus(III)-Centered Cations [LPX 2 ] + and [L 2 PX] 2+ (L = NHC; X = Cl, CN, N 3 )

有机磷化合物合成

NHC配体化学

A versatile, high-yielding synthesis of NHC-stabilized [PCl2]+ and [PCl]2+ phosphorus synthons has been achieved by using an “onio-substituent transfer” reagent. Subsequent functionalization yields ac

NIAID Data Ecosystem10

NHC-Mediated Aggregation of P 4 : Isolation of a P 12 Cluster

磷簇合成

NHC配体化学

Just like transition metal complexes, N-heterocyclic carbenes (NHCs) promote the aggregation of white phosphorus (P4) as shown by the high yield synthesis of a P12 cluster capped by two NHCs. The nucl

NIAID Data Ecosystem20

Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity

过渡金属催化交叉偶联

NHC配体化学

Compounds of general formula [Pd(L)(NHC)(L′)]BF4 (where L = allyl or crotyl, NHC = tetramethylimidazolin-2-ylidene (tmiy) or 1,3-diisopropyl-4,5-dimethylimidazolin-2-ylidene (dipdmiy), and L′ = tertia

NIAID Data Ecosystem20

Replication data for: Understanding Synthetic Peculiarities of Cationic Molyb...

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