Synthesis of d<sup>2</sup> Tungsten Arene Complexes and Their Reaction with Diphenylacetylene
收藏NIAID Data Ecosystem2026-03-06 收录
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The synthesis of the d2 arene complexes [W(NPh)(η6-arene)(o-(Me3SiN)2C6H4)] (arene = C6H5Et (3), C6H5Pr (4)) by the room-temperature hydrogenolysis of the dialkyl complexes [W(NPh)(o-(Me3SiN)2C6H4)(R)2] (R = CH2CH2Ph (1), CH2CH2CH2Ph (2)) is described. The ethylbenzene complex 3 reacts with diphenylacetylene, giving the metallacyclopent-3-ene complex 5.
创建时间：
2016-08-26
