Core/Shell Oligometallic Template Synthesis of Macrocyclic Hexaoxime
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https://figshare.com/articles/dataset/Core_Shell_Oligometallic_Template_Synthesis_of_Macrocyclic_Hexaoxime/3012532
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资源简介：
A 36-membered macrocyclic hexaoxime was quantitatively obtained
by [3 + 3] condensation of dialdehyde 2 with diamine 3 using
La3+ (core metal) and Zn2+ (shell metal) as a novel core/shell
template, while the yield was very low in the absence of the metal
ions. The high yield can be attributed to the efficient formation of
a 3:3:1 complex of dialdehyde 2, Zn2+, and La3+, which readily
gives the macrocycle keeping the Zn3La core/shell tetranuclear
cluster structure.
创建时间：
2016-02-29
