Spontaneous Resolution of a New Thiogermanate Containing Chiral Binuclear Nickel(II) Complexes with Achiral Triethylenetetramine Ligands: A Unique Water-Mediated Supramolecular Hybrid Helix
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Spontaneous_Resolution_of_a_New_Thiogermanate_Containing_Chiral_Binuclear_Nickel_II_Complexes_with_Achiral_Triethylenetetramine_Ligands_A_Unique_Water_Mediated_Supramolecular_Hybrid_Helix/2626604
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资源简介：
The first homochiral binuclear metal complex cation-containing inorganic–organic hybrid chalcogenidometalates [Ni2(teta)3](Ge4S10)·H2O (1 and 1′; teta = triethylenetetramine) were prepared, which spontaneously separate in enantiomers upon crystallization; a unique water-mediated hybrid supramolecular helix, and the correlation between molecular chirality and absolute helicity are observed in the entantiomers.
创建时间：
2016-02-23
