Spontaneous Resolution of a New Thiogermanate Containing Chiral Binuclear Nickel(II) Complexes with Achiral Triethylenetetramine Ligands: A Unique Water-Mediated Supramolecular Hybrid Helix
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The first homochiral binuclear metal complex cation-containing inorganic–organic hybrid chalcogenidometalates [Ni2(teta)3](Ge4S10)·H2O (1 and 1′; teta = triethylenetetramine) were prepared, which spontaneously separate in enantiomers upon crystallization; a unique water-mediated hybrid supramolecular helix, and the correlation between molecular chirality and absolute helicity are observed in the entantiomers.
创建时间：
2016-02-23
