five

Oxidative Dehydrogenative Couplings of Pyrazol-5-amines Selectively Forming Azopyrroles

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https://figshare.com/articles/dataset/Oxidative_Dehydrogenative_Couplings_of_Pyrazol_5_amines_Selectively_Forming_Azopyrroles/2032557
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New oxidative dehydrogenative couplings of pyrazol-5-amines for the selective synthesis of azopyrrole derivatives have been described. The former reaction simultaneously installs C–I and N–N bonds through iodination and oxidation, whereas the latter involved a copper-catalyzed oxidative coupling process. The resulting iodo-substituted azopyrroles were employed by treatment with various terminal alkynes through Sonogashira cross-coupling leading to new azo compounds.
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2015-12-17
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