Reactions of [CpRuCl(PP)] (PP = dppm, dppe) with NaBAr‘4: Structural Characterization of [{CpRu}2(μ-Cl)(μ-dppm)2][BAr‘4] and of [Cp*Ru(N2)(dppm)][BAr‘4] (Ar‘ = 3,5-C6H3(CF3)2)

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https://figshare.com/articles/dataset/Reactions_of_Cp_RuCl_PP_PP_dppm_dppe_with_NaBAr_sub_4_sub_Structural_Characterization_of_Cp_Ru_sub_2_sub_-Cl_-dppm_sub_2_sub_BAr_sub_4_sub_and_of_Cp_Ru_N_sub_2_sub_dppm_BAr_sub_4_sub_Ar_3_5-C_sub_6_sub_H_sub_3_sub_CF_sub_3_sub_sub_2_sub_/3774597 数据链接链接失效反馈

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资源简介：

The reaction of [Cp*RuCl(dppm)] with NaBAr‘4 in fluorobenzene under argon generates the binuclear complex [{Cp*Ru}2(μ-Cl)(μ-dppm)2][BAr‘4], which has been structurally characterized. No complex was isolated from the reaction of [Cp*RuCl(dppe)] with NaBAr‘4 under argon, but halide abstraction from [Cp*RuCl(PP)] (PP = dppm, dppe) under dinitrogen using NaBAr‘4 yielded the corresponding cationic terminal dinitrogen complexes [Cp*Ru(N2)(PP)][BAr‘4].

创建时间：

2016-08-26

Reactions of [Cp*RuCl(PP)] (PP = dppm, dppe) with NaBAr‘<sub>4</sub>: Structural Characterization of [{Cp*Ru}<sub>2</sub>(μ-Cl)(μ-dppm)<sub>2</sub>][BAr‘<sub>4</sub>] and of [Cp*Ru(N<sub>2</sub>)(dppm)][BAr‘<sub>4</sub>] (Ar‘ = 3,5-C<sub>6</sub>H<sub>3</sub>(CF<sub>3</sub>)<sub>2</sub>)

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相关数据集

Reactions of [CpRuCl(PP)] (PP = dppm, dppe) with NaBAr‘<sub>4</sub>: Structural Characterization of [{CpRu}<sub>2</sub>(μ-Cl)(μ-dppm)<sub>2</sub>][BAr‘<sub>4</sub>] and of [Cp*Ru(N<sub>2</sub>)(dppm)][BAr‘<sub>4</sub>] (Ar‘ = 3,5-C<sub>6</sub>H<sub>3</sub>(CF<sub>3</sub>)<sub>2</sub>)