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Addition of Difluoromethyl Radicals to Glycals: A New Route to α-<i>CF</i><sub>2</sub>-d-Glycosides

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NIAID Data Ecosystem2026-03-06 收录
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The synthesis of synthetically useful α-CF2-glycosides by radical addition of ethyl bromodifluoroacetate onto 2-benzyloxyglycals is described. The methodology provides an access to α-O-glycoside mimics and, potentially, to valuable α-O-glycoconjugate analogues.

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2007-06-21
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