Reactions of Titanium Hydrazides with Silanes and Boranes: N–N Bond Cleavage and N Atom Functionalization
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https://figshare.com/articles/dataset/Reactions_of_Titanium_Hydrazides_with_Silanes_and_Boranes_N_N_Bond_Cleavage_and_N_Atom_Functionalization/2201725
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资源简介：
Reaction of Ti(N2iPrN)(NNPh2)(py) with Ph(R)SiH2 (R = H, Ph) or 9-BBN gave reductive
cleavage of the Nα–Nβ bond
and formation of new silyl- or boryl-amido ligands. The corresponding
reactions of Cp*Ti{MeC(NiPr)2}(NNR2) (R = Me or Ph) with HBPin or 9-BBN gave borylhydrazido-hydride
or borylimido products, respectively. Nα and Nβ atom transfer and dehydrogenative coupling reactions
are also reported.
创建时间：
2016-02-15
