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Anionic Annulation of 3‑Cyanophthalides with Allene Carboxylates: A Carbon-Conserved Synthesis of Naphtho[<i>b</i>]furanones

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NIAID Data Ecosystem2026-03-10 收录
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The reaction of 3-cyanophthalides with allene carboxylates in the presence of tBuOLi results in a tandem annulation furnishing naphtho­[b]­furanones in good yields with no loss of carbon. The carbon economy is explained by a tandem process, in which the initially expelled cyanide induces the second annulation.

创建时间:
2018-04-02
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