UV-Light-Induced N‑Acylation of Amines with α‑Diketones
收藏NIAID Data Ecosystem2026-03-12 收录
下载链接：
https://figshare.com/articles/dataset/UV-Light-Induced_N_Acylation_of_Amines_with_Diketones/14869293
下载链接
链接失效反馈官方服务：
资源简介：
Herein, we develop a mild method
for N-acylation
of primary and secondary amines with α-diketones induced by
ultraviolet (UV) light. Forty-six examples with various functional
groups are explored at room temperature with irradiation by three
26 W UV lamps (350–380 nm). The yield reaches 97%. The gram
scale experiment product yield is 76%. Moreover, this system can be
applied to the synthesis of several amino acid derivatives. Mechanistic
studies show that benzoin is generated in situ from
benzil under UV irradiation.
创建时间：
2021-06-28
