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Structural Characterization and Luminescence Behavior of a Silver(I) 1D Polymeric Chain Constructed via a Bridge with Unusual 4,5-Diazospirobifluorene and Perchlorate

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Structural_Characterization_and_Luminescence_Behavior_of_a_Silver_I_1D_Polymeric_Chain_Constructed_via_a_Bridge_with_Unusual_4_5_Diazospirobifluorene_and_Perchlorate/3329314
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A new polymeric silver complex, [Ag2(L2)(ClO4)2] (L = 4,5-diazospirobifluorene), has been synthesized and shown to exhibit interesting luminescence properties in a single crystal. Structural analysis reveals a one-dimensional chain, which contains a [Ag2(L2)]2+ dimer bridged with ClO4-. The Ag···Ag distances are 2.776(1) and 4.575(1) Å incorporated by two L ligands and by a ClO4- bridge, respectively.
创建时间:
2016-05-06
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