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Assessment of the Jahn-Teller effect in magnetostrictive (Ni,Zn) spinel ferrites by multiwavelength diffraction

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DataCite Commons2026-04-06 更新2026-05-03 收录
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https://doi.esrf.fr/10.15151/ESRF-ES-2332872788
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This work aims to develop a better grasp on the cooperative Jahn-Teller (CJT) effect, to mitigate the detrimental effect of magnetostriction on electromagnetic properties of soft ferrites. Mn3+ and Cu2+ ions in octahedral sites have a Jahn-Teller (JT) effect, inducing structural deformation, breaking its symmetry to lift the degeneracy of eg orbitals. X-ray powder diffraction with a synchrotron source could help observe lattice deformations in Ni-Zn-Cu and Ni-Zn-Mn ferrites. Measurements on the BM02-D2AM beamline will enable to determine the Mn/Cu concentration threshold and strength of a CJT effect, leading to a better understanding of the role of symmetry breaking on spin-orbit coupling.
提供机构:
European Synchrotron Radiation Facility
创建时间:
2026-04-06
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