Platinum Stannaborate Complexes: Activated Isonitrile Insertion
收藏NIAID Data Ecosystem2026-03-06 收录
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The stannaborate complexes {(Ph3P)(H11B11Sn)Pt(tBuNC)[C(Ph)NHtBu]} (2) and {(dppe)(H11B11Sn)Pt[C(Ph)NHtBu]} (4) were obtained by insertion of tBuNC into the Pt−Ph bond of [Bu3MeN][trans-(Ph3P)2Pt(Ph)(SnB11H11)] and [Bu3MeN][(dppe)Pt(Ph)(SnB11H11)] at room temperature. The insertion products were characterized by elemental analysis, NMR spectroscopy, and X-ray crystal structure analysis.
创建时间:
2016-08-26



