Data on synthesis and characterization of sulfonated poly(phenylnorbornene) and polymer electrolyte membranes based on it

This dataset obtained from the synthesis and characterization of sulfonated poly (norbornene) and ionic polymer membranes based on it. The polymer was synthesized via one-pot two step ring-opening metathesis polymerization (ROMP) and subsequent reduction by p-toluenesulfonyl hydrazide. The dataset contains raw spectra and thermal data of hydrated poly (phenyl norbornene) (HPPhNB), sulfonated hydrated poly (phenyl norbornene) (SHPPhNB), imidazolium sulfonated hydrated poly (phenyl norbornene) (SHPPhNB-Im) and 1-methylimidazolium sulfonated hydrated (phenyl norbornene) (SHPPhNB-MIm) as 1H NMR free induction decays (FID), raw FTIR spectra and DSC curves. Data from electrochemical impedance spectroscopy (EIS) for membranes prepared from ionomers and blend with PVDF membranes are provided. Images of both surfaces and cross-section of blend membranes obtained by scanning electron microscopy (SEM) are presented.本数据集源于磺化聚降冰片烯（sulfonated poly(norbornene)）及其衍生离子聚合物膜的合成与表征工作。该聚合物通过一锅两步开环易位聚合（ROMP）法合成，后续经对甲苯磺酰肼还原制得。 本数据集包含水化聚(苯基降冰片烯)（hydrated poly(phenyl norbornene), HPPhNB）、磺化水化聚(苯基降冰片烯)（sulfonated hydrated poly(phenyl norbornene), SHPPhNB）、咪唑鎓磺化水化聚(苯基降冰片烯)（imidazolium sulfonated hydrated poly(phenyl norbornene), SHPPhNB-Im）以及1-甲基咪唑鎓磺化水化(苯基降冰片烯)（1-methylimidazolium sulfonated hydrated (phenyl norbornene), SHPPhNB-MIm）的原始谱图与热学数据，具体包括氢核磁共振（1H NMR）自由感应衰减（FID）数据、原始傅里叶变换红外（FTIR）谱图及差示扫描量热法（DSC）曲线。 本数据集还提供了离聚物制备膜及与聚偏氟乙烯（PVDF）共混膜的电化学阻抗谱（EIS）测试数据。此外，数据集收录了通过扫描电子显微镜（SEM）获取的共混膜表面与截面形貌图像。