Cs10H[Ga3H8]3: A Hydrogenous Zintl phase Containing Propane-Like Polyanions [Ga3H8]3– and Interstitial Hydrogen
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Cs_sub_10_sub_H_Ga_sub_3_sub_H_sub_8_sub_sub_3_sub_A_Hydrogenous_Zintl_phase_Containing_Propane_Like_Polyanions_Ga_sub_3_sub_H_sub_8_sub_sup_3_sup_and_Interstitial_Hydrogen/2404909
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The hydrogenous Zintl-phase Cs10H[Ga3H8]3 containing propane-like polyanions [Ga3H(D)8]3– was successfully synthesized by direct hydrogenation of a 1:1 Cs/Ga metal mixture and characterized by powder X-ray and neutron diffraction. The charge of the polyanions is balanced by two different species of cations, hydrogen-centered octahedra [H(D)Cs6]5+ and isolated Cs+. The structure crystallizes in the hexagonal space group P63/mcm (193) with the cell parameters a = 11.1108(3) Å, c = 18.2149(5) Å, Z = 2.
创建时间：
2016-02-19
