Preparation and C−X Reductive Elimination Reactivity of Monoaryl Pd<sup>IV</sup>−X Complexes in Water (X = OH, OH<sub>2</sub>, Cl, Br)
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Monohydrocarbyl palladium(IV) complexes bearing OH, OH2, Br, and Cl ligands at the metal and supported by facially chelating 1-hydroxy-1,1-bis(2-pyridyl)methoxide were readily prepared in water at 0 °C. These complexes reductively eliminate Ar−X (X = OH, Br, Cl) in water at room temperature in high yield, and the corresponding first-order rate constants kOH, kCl, and kBr are on the same order of magnitude.
创建时间：
2010-10-20
