Metal–Organic Proximity in a Synthetic Pocket
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https://figshare.com/articles/dataset/Metal_Organic_Proximity_in_a_Synthetic_Pocket/2320012
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资源简介：
Proximity
between a noninteractive organic substrate and a transition
metal (trans-MCl2(PEt3)2; M = Pd or Pt) is achieved by their co-encapsulation within
a synthetic cage, as revealed by X-ray crystallographic analysis and
NOESY experiments. Through co-encapsulation with a Pd(II) complex,
a terminal alkyne was activated within the cage to give a σ-alkynylpalladium
complex.
创建时间：
2014-02-26
