Catalytic Intermolecular Hydroamination of Methylenecyclopropanes
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https://figshare.com/articles/dataset/Catalytic_Intermolecular_Hydroamination_of_Methylenecyclopropanes/3258844
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资源简介：
The octahedral titanium catalyst Ti(Ph2PNpy)2(NEt2)2 (1) was found to be an efficient catalyst
for the hydroamination of methylenecyclopropane with
either aromatic or aliphatic amines. For a symmetrical
methylenecyclopropane, only one product is obtained in
high yield. The reaction of complex 1 with ethylamine
and aniline produces the dimeric titanium complexes
Ti2(Ph2PNpy)2(μ-NEt)2 and Ti2(Ph2PNpy)2(μ-NPh)2, respectively.
创建时间：
2005-11-07
