Synthesis and Characterization of Ferrocene-Chelating Heteroscorpionate Complexes of Nickel(II) and Zinc(II)
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Ferrocene_Chelating_Heteroscorpionate_Complexes_of_Nickel_II_and_Zinc_II_/2196205
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资源简介：
The first example of a ferrocene-chelating
heteroscorpionate, [Li(THF)2][fc(PPh2)(BH[(3,5-Me)2pz]2)] ((fcP,B)Li(THF)2,
fc = 1,1′-ferrocenediyl) is described. Starting from a previously
reported compound, fcBr(PPh2), a series of ferrocene derivatives,
fc(PPh2)(B[OMe]2), [Li(OEt2)][fc(PPh2)(BH3)], [Li(THF)2][fc(PPh2)(BH[(3,5-Me)2pz]2)] (pz = pyrazole), was isolated
and characterized. Compound (fcP,B)Li(THF)2 allowed
the synthesis of the corresponding nickel and zinc complexes, (fcP,B)NiCl, (fcP,B)NiMe, (fcP,B)ZnCl, and
(fcP,B)ZnMe. All compounds were characterized by NMR spectroscopy,
while the zinc and nickel complexes were also characterized by X-ray
crystallography. The redox behavior of (fcP,B)NiCl, (fcP,B)NiMe, (fcP,B)ZnCl, and (fcP,B)ZnMe
was studied by cyclic voltammetry and supported by density functional
theory calculations.
创建时间：
2016-02-14
