Total Synthesis of Asterredione
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https://figshare.com/articles/dataset/Total_Synthesis_of_Asterredione/2316802
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The
first total synthesis of asterredione was efficiently accomplished
over five linear steps and in 21.5% overall yield. As the crucial
step, the 2-quaternary 1,3-cyclopentenedione skeleton of asterredione
was readily achieved using the Darzens/ring-expansion strategy developed
in our laboratory. The structure of synthesized asterredione was fully
confirmed by X-ray crystallography.
创建时间:
2016-02-18



