Intervalence Charge-Transfer System by 1D Assembly of New Mixed-Valence Octanuclear CuI/CuII/CuIII Cluster Units
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Intervalence_Charge_Transfer_System_by_1D_Assembly_of_New_Mixed_Valence_Octanuclear_Cu_sup_I_sup_Cu_sup_II_sup_Cu_sup_III_sup_Cluster_Units/2670316
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The reaction of Cu(Hm-dtc)2, Br2, and CuBr2 yielded a new mixed-valence octanuclear CuI/CuII/CuIII cluster, encapsulating a Br anion in the center of the cluster cage. The octanuclear cluster units form a 1D assemblage, which induces intervalence charge-transfer transitions from CuII ions to CuIII ions between the clusters.
创建时间：
2016-02-23
