Intervalence Charge-Transfer System by 1D Assembly of New Mixed-Valence Octanuclear CuI/CuII/CuIII Cluster Units
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The reaction of Cu(Hm-dtc)2, Br2, and CuBr2 yielded a new mixed-valence octanuclear CuI/CuII/CuIII cluster, encapsulating a Br anion in the center of the cluster cage. The octanuclear cluster units form a 1D assemblage, which induces intervalence charge-transfer transitions from CuII ions to CuIII ions between the clusters.
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2016-02-23
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