Magnetic Nanosized {MII24}-Wheel-Based (M = Co, Ni) Coordination Polymers
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Two 3D coordination polymers, [Co24(OH)12(SO4)12(ip)6(DMSO)18(H2O)6]·(DMSO)6(EtOH)6(H2O)36 (1·guests, ip = isophthalate) and [Ni24(OH)12(SO4)12(ip)6(DMSO)12(H2O)12]·(DMSO)6(EtOH)6(H2O)20 (2·guests), constructed with nanosized tetraicosanuclear CoII and NiII wheels are solvothermally synthesized. Both complexes show intra- and interwheel dominant antiferromagnetic interactions.
创建时间：
2016-02-20
