Intramolecular Direct C–H Arylation via a Metallocenic Radical Pathway: Stereospecific Approach to Planar-Chiral Ferrocenes
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https://figshare.com/articles/dataset/Intramolecular_Direct_C_H_Arylation_via_a_Metallocenic_Radical_Pathway_Stereospecific_Approach_to_Planar-Chiral_Ferrocenes/5476936
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资源简介:
Transition
metal-free synthesis of planar-chiral 1,2-fused ferrocenes
via intramolecular direct C–H bond arylation was achieved.
The C–H arylation reactions promoted by a catalytic amount
of 1,10-phenanthroline highlighted a unique planar-chiral metallocenic
radical intermediate, generated from iodoferrocenes via a single-electron
transfer process.
创建时间:
2017-10-05



