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Ni-Catalyzed Highly Chemo‑, Regio‑, and Enantioselective Decarboxylative Aldol Reaction of β,γ-Unsaturated α‑Ketoesters with β‑Ketoacids

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https://figshare.com/articles/dataset/Ni_Catalyzed_Highly_Chemo_Regio_and_Enantioselective_Decarboxylative_Aldol_Reaction_of_Unsaturated_Ketoesters_with_Ketoacids/2175442
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资源简介:
A novel Ni-catalyzed decarboxylative aldol reaction of β,γ-unsaturated α-ketoesters with β-ketoacids is reported. The reaction proceeds smoothly with high chemo-, regio-, and enantioselectivity. This protocol provides a convenient approach to access enantioenriched chiral tertiary alcohols.
创建时间:
2016-02-13
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