Evolution of diagenetic fluids in the deeply buried, upper Ediacaran Dengying Formation, Central Sichuan Basin, China

Deeply buried Precambrian carbonate reservoirs host economic petroleum reserves. The upper Ediacaran Dengying Formation (maximum burial depth >8 km) is predominantly composed of dolostone with porosity ranging from 2 to 4%, and minor limestone with a porosity of <2%. Detailed petrological observations and high-resolution geochemical analyses show the evolution from depositional fluids to late diagenetic fluids. Dolostone is subdivided into dolo-mudstone, dolo-laminite, stromatolitic dolostone, thrombolitic dolostone and oncoidal dolostone. These dolostones were precipitated from the Ediacaran seawater and yield rare earth elements and yttrium (REY) patterns similar to those of modern seawater. In the early diagenetic regimes, fibrous dolomite cement, characterised by superchondritic Y/Ho ratios, was first precipitated from marine porewaters, and then fine-crystalline dolomite cement, characterised by low Y/Ho ratios, was formed during meteoric diagenesis. Bladed dolomite cement was subsequently precipitated from (modified) seawater-dominated porewaters. In the intermediate burial regimes, medium- to coarse-crystalline dolomite cement was formed during reduction of Mn oxides. In the deep-burial regimes, saddle dolomite was precipitated from hydrothermal fluids and yields REY patterns characterised by MREE enrichment. Its superchondritic Y/Ho ratios were likely caused by the fractionation between Y and Ho during the co-precipitation of fluorite. Calcite cement has similar parent fluids to those of saddle dolomite. These dolomite phases have similar δ13C values, while their δ18O values gradually decrease during the paragenetic sequence. Multiphase dolomitisation led to the increase in Ca/Mg ratios of formation water and reservoir performance. This study is significant for those concerned with the deeply buried dolostone reservoirs. KEY POINTS
Microbialites and five types of dolomite cements have different REY patterns.
Co-precipitation of fluorite led to the superchondritic Y/Ho ratios of dolomite.
Dolomite and calcite grains show micro-scale geochemical variations.
This dolostone reservoir underwent multiphase fluids, including meteoric water, seawater and hydrothermal fluid.

Microbialites and five types of dolomite cements have different REY patterns.
Co-precipitation of fluorite led to the superchondritic Y/Ho ratios of dolomite.
Dolomite and calcite grains show micro-scale geochemical variations.
This dolostone reservoir underwent multiphase fluids, including meteoric water, seawater and hydrothermal fluid.