A Percyanovinylidene−Ruthenium Complex, Ru{CC<sub>5</sub>(CN)<sub>3</sub>[C(CN)<sub>2</sub>]<sub>2</sub>}(dppe)Cp*
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资源简介：
The reaction between Ru(CCCCAg)(dppe)Cp* and tcne affords a novel percyanovinylidene complex by an unusual decyano-dimerization reaction of the cyanocarbon with the diynyl fragment. This complex is also obtained from tcne and Ru{CCCC[Au(PPh3)]}(dppe)Cp*, together with Ru{CCC[C(CN)2]C[Au(PPh3)]C(CN)2}(dppe)Cp*, formed by the anticipated [2 + 2] cycloaddition and subsequent ring-opening reactions.
创建时间：
2011-02-14
