Allylation of Donor−Acceptor Cyclopropanes
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https://figshare.com/articles/dataset/Allylation_of_Donor_Acceptor_Cyclopropanes/3358552
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Direct allylation of glycal-derived donor−acceptor cyclopropanes has been achieved with TiCl4 activation followed by addition of
allyltrimethylsilane. The α diastereomer is the major product, with selectivities ranging from 3:1 to 10:1 and yields around 80%.
创建时间:
2016-05-07



