Tripodal Phenylamine-Based Ligands and Their Co<sup>II</sup> Complexes
收藏NIAID Data Ecosystem2026-03-06 收录
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The syntheses of two phenylamine-based ligand systems, N(o-PhNH2)3 and N(o-PhNHC(O)iPr)3, are reported. These ligands readily coordinate to CoII to form monomeric complexes. X-ray diffraction studies establish that the [N(o-PhNC(O)iPr)3]3- ligand stabilizes the CoII ion in a trigonal-monopyramidal coordination environment. The axial coordination site in this complex is accessible and, upon cyanide coordination, generates an electrochemically active species.
创建时间：
2016-06-03
