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Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex

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NIAID Data Ecosystem2026-03-10 收录
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Reduction of IU­(NHAriPr6)2 (AriPr6 = 2,6-(2,4,6-iPr3C6H2)2C6H3) results in a rare example of a U­(II) complex, U­(NHAriPr6)2, and the first example that is a neutral species. Here, we show spectroscopic and magnetic studies that suggest a 5f46d0 valence electronic configuration for uranium, along with characterization of related U­(III) complexes.

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2018-12-04
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