From Bifunctional Nucleophilic Behavior of DBU to a New Heterocyclic Fluorescent Platform
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https://figshare.com/articles/dataset/From_Bifunctional_Nucleophilic_Behavior_of_DBU_to_a_New_Heterocyclic_Fluorescent_Platform/3054016
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资源简介:
An unexpected discovery of a novel cyclocondensation reaction of 1,8-diazabicyclo[5.4.0]undec-8-ene (DBU) with activated 1,2-dichloro compounds
is described. The 2-aminopyrrole skeleton is generated through the concomitant formation of new nitrogen−carbon and carbon−carbon bonds.
A new pentacyclic derivative formed upon the reaction of 2,3-dichloroquinoxaline with DBU exhibits strong fluorescence both in solutions (Φ
in hexane = 0.4) and in the solid state.
创建时间:
2016-02-29



