Chiral Transfer in the Reaction of Aminoallylic Stannanes with Carbonyls in Two Different Modes using Tin(II) and Indium(III) Halides for the Synthesis of Each Enantiomer
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https://figshare.com/articles/dataset/Chiral_Transfer_in_the_Reaction_of_Aminoallylic_Stannanes_with_Carbonyls_in_Two_Different_Modes_using_Tin_II_and_Indium_III_Halides_for_the_Synthesis_of_Each_Enantiomer/2266981
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资源简介：
The
reaction of homochiral aminoallylic stannanes with aldehydes
gave carbonyl adducts of amino alcohols in the presence of either
SnCl2 or InBr3. Both additives afforded the
products in opposite absolute stereochemical configurations. The controlled
chirality was ascribed to the different transmetalation pathways of
SnCl2 and InBr3.
创建时间：
2016-02-17
