Silylation-Based Kinetic Resolution of α‑Hydroxy Lactones and Lactams
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A silylation-based kinetic resolution has been developed for α-hydroxy lactones and lactams employing the chiral isothiourea catalyst (−)-benzotetramisole and triphenylsilyl chloride as the silyl source. The system is more selective for lactones than lactams, and selectivity factors up to 100 can be achieved utilizing commercially available reagents.
创建时间：
2016-02-18
