Enantioselective Rhodium-Catalyzed Alkenylation of Aliphatic Imines
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https://figshare.com/articles/dataset/Enantioselective_Rhodium-Catalyzed_Alkenylation_of_Aliphatic_Imines/5481373
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资源简介:
An efficient, enantioselective rhodium-catalyzed
addition of potassium
alkenyltrifluoroborates to N-nosyl aliphatic imines
has been realized. Good reaction yields and excellent enantioselectivities
(94–99% ee) were obtained for a variety of aliphatic imines
and nucleophilic alkenyltrifluoroborates. An active rhodium-diene
catalyst and the precise reaction condition control proved to be pivotal
for success.
创建时间:
2017-10-09



