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Enantioselective Rhodium-Catalyzed Alkenylation of Aliphatic Imines

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NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Enantioselective_Rhodium-Catalyzed_Alkenylation_of_Aliphatic_Imines/5481373
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An efficient, enantioselective rhodium-catalyzed addition of potassium alkenyltrifluoroborates to N-nosyl aliphatic imines has been realized. Good reaction yields and excellent enantioselectivities (94–99% ee) were obtained for a variety of aliphatic imines and nucleophilic alkenyltrifluoroborates. An active rhodium-diene catalyst and the precise reaction condition control proved to be pivotal for success.
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2017-10-09
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