Synthesis and Characterization of Cobalt Complexes with Radical Anionic α‑Diimine Ligands
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Cobalt_Complexes_with_Radical_Anionic_Diimine_Ligands/2345365
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资源简介：
Three
cobalt complexes, [LCo(μ-Cl)]2·THF·Et2O (1), [LCo(η6-toluene)] (2), and [LCo]2 (3), where L = [(2,6-iPr2C6H3)NC(Me)]2, have been synthesized from reduction of the dichloro cobalt precursor
[LCoCl2] by sodium or potassium metal. Single-crystal X-ray
diffraction analyses reveal that the complexes display novel structures
with the singly reduced form (L•–) of the
α-diimine ligand: the dichloro-bridged binuclear complex 1, the mononuclear 2 with an η6-coordinated toluene molecule, and the dimer 3 through
Co–aryl interactions of two [LCo] units. The compounds were
further characterized by EPR and magnetic studies.
创建时间：
2016-02-18
