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Helical Self-Assembly and Photopolymerization Properties of Achiral Amphiphilic Platinum(II) Diacetylene Complexes of Tridentate 2,6-Bis(1-alkylpyrazol-3-yl)pyridines

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https://figshare.com/articles/dataset/Helical_Self-Assembly_and_Photopolymerization_Properties_of_Achiral_Amphiphilic_Platinum_II_Diacetylene_Complexes_of_Tridentate_2_6-Bis_1-alkylpyrazol-3-yl_pyridines/3464402
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资源简介:
Amphiphilic platinum­(II) diacetylene complexes of the 2,6-bis­(1-butylpyrazol-3-yl)­pyridine pincer ligand were designed and synthesized. Helical fibrous nanostructures were obtained through supramolecular assembly of the achiral platinum­(II) diacetylene complexes via intermolecular hydrogen bonding, amphiphilic effects, Pt···Pt interactions, and π–π stacking interactions. In situ post-photopolymerization of the diacetylene unit was shown to occur in the preorganized helical fibers.
创建时间:
2016-07-07
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