Use of Alkylsodium Reagents for the Synthesis of Trivalent Uranium Alkyl Complexes
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https://figshare.com/articles/dataset/Use_of_Alkylsodium_Reagents_for_the_Synthesis_of_Trivalent_Uranium_Alkyl_Complexes/2511259
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资源简介：
A family of rare uranium(III) alkyl complexes, Tp*2UR
(R = CH2SiMe3 (3-CH2SiMe3), CH3 (4-CH3), (CH2)3CH3 (5-(CH2)3CH3); Tp* = hydrotris(3,5-dimethylpyrazolyl)borate), was
synthesized by salt metathesis with alkylsodium reagents and Tp*2UI (2). All compounds were fully characterized
using 1H NMR, infrared, and electronic absorption spectroscopies.
Compounds 3-CH2SiMe3 and 4-CH3 were structurally characterized using X-ray crystallography
and have U–C bond distances of 2.601(9) and 2.54(3) Å,
respectively.
创建时间：
2016-02-20
