Methoxide of an Anderson-Type Polyoxometalate and Its Conversion to a New Type of Species, [IMo<sub>9</sub>O<sub>32</sub>(OH)(OH<sub>2</sub>)<sub>3</sub>]<sup>4-</sup><sup>†</sup>
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A totally new type of polyoxometalate, [IMo9O32(OH)(OH2)3]4-, has been synthesized by reacting [IMo6O22(OMe)2]3- with water. The [IMo9O32(OH)(OH2)3]4- anion further transforms into [(IMo7O26)2]6-, a molecular oxide that has a rutile core, in dry acetonitrile, while it stays intact for several hours in wet acetonitrile.
创建时间:
2016-05-05



