Double Metalation of Acetone by a Nickel–NHC Complex: Trapping of an Oxyallyl Ligand at a Dinickel Center
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https://figshare.com/articles/dataset/Double_Metalation_of_Acetone_by_a_Nickel_NHC_Complex_Trapping_of_an_Oxyallyl_Ligand_at_a_Dinickel_Center/2573443
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资源简介：
We report the first example of a structurally characterized
oxyallyl
−CH2C(O)CH2– group, trapped as
a bridging ligand that spans two nickel centers. The ligand results
from the double metalation of acetone on a nickel–NHC platform.
A competing reaction leads to a single metalation of acetone.
创建时间：
2016-02-22
