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Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer

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https://figshare.com/articles/dataset/Palladium_Induced_Macrocyclic_Preorganization_for_Stabilization_of_a_Tetrathiafulvalene_Mixed_Valence_Dimer/2613688
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Ditopic metalation of a flexible “Pacman”-like tetrathiafulvalene (TTF) modified Schiff-base-calixpyrrole results in the stabilization upon oxidation of an otherwise difficult-to-access mixed-valence TTF radical dimer. EPR and optical spectroscopies were used to characterize the mixed-valence species.
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2011-09-16
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