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Pd-Catalyzed Enantioselective Hydroalkoxylation of Alkoxyallenes with Phenol for Construction of Acyclic O,O‑Acetals

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Figshare2016-02-14 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Pd_Catalyzed_Enantioselective_Hydroalkoxylation_of_Alkoxyallenes_with_Phenol_for_Construction_of_Acyclic_i_O_i_i_O_i_Acetals/2189473
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Palladium-catalyzed asymmetric intermolecular hydroalkoxylation of allenes has been developed by using phenol as a pronucleophile. Acyclic O,O-acetals were obtained in high yields (up to 98%) with good to excellent enantiomeric excesses (up to 94% ee).
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2016-02-14
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