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Formation of Linear Tetramers of Diarylalkynes by the Zr/Cr System

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https://figshare.com/articles/dataset/Formation_of_Linear_Tetramers_of_Diarylalkynes_by_the_Zr_Cr_System/3270682
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The reaction of diarylalkynes with Cp2ZrBu2 and successive treatment with CrCl3 afforded linear tetramers of diarylalkynes, (1E,3E,5E,7E)-octatetraenes. On the other hand, dialkylalkynes did not give the corresponding octatetraenes but cyclized products, such as pyridines and pyridones, by the reaction with nitriles and isocyanates.
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2005-08-31
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