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Elements as Direct Feedstocks for Organic Synthesis: Fe/I2/O2 for Diamination of 2‑Cyclohexenones with 2‑Aminopyrimidine and 2‑Aminopyridines

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Figshare2016-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Elements_as_Direct_Feedstocks_for_Organic_Synthesis_Fe_I_sub_2_sub_O_sub_2_sub_for_Diamination_of_2_Cyclohexenones_with_2_Aminopyrimidine_and_2_Aminopyridines/2120965
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Elements as feedstocks for organic synthesis, the trio of metallic iron, molecular iodine, and dioxygen, were found to be an excellent tool for oxidative regioselective diamination of conjugated enones with 2-aminopyrimidine (a guanidine surrogate) and 2-aminopyridines leading to unaromatized coupled products in moderate to good yields.
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2016-02-12
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